Issue 96, 2013
From the journal:

Chemical Communications

Modular structure of a robust microporous MOF based on Cu2 paddle-wheels with high CO2 selectivity†

José M. Seco,a   David Fairen-Jimenez,*b   Antonio J. Calahorro,c   Laura Méndez-Liñán,c   Manuel Pérez-Mendoza,c   Nicola Casati,d   Enrique Colacioc  and  Antonio Rodríguez-Diéguez*c  

* Corresponding authors

a Departamento de Química Aplicada, Facultad de Ciencias Químicas de San Sebastián, Universidad del País Vasco, Spain

b Dept. of Chemical Engineering & Biotechnology, University of Cambridge, Pembroke Street, Cambridge CB2 3RA, UK
E-mail: df334@cam.ac.uk
Web: http://people.ds.cam.ac.uk/df334

c Departamento de Química Inorgánica, Universidad de Granada, Avda Fuentenueva s/n, Granada, Spain
E-mail: antonio5@ugr.es

d Paul Scherrer Institute, WLGA/229, Villigen PSI, Switzerland

Abstract

The synthesis of a new MOF with Cu2 paddle-wheels connected to glutarate and 1,3-bis(4-pyridyl)propane linkers has been explored. Experimental gas adsorption measurements reveal that the MOF is essentially non-porous to methane whereas it presents a type III isotherm upon CO2 adsorption, leading to high capacity and outstanding CO2 selectivity.

Graphical abstract: Modular structure of a robust microporous MOF based on Cu2 paddle-wheels with high CO2 selectivity

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Article information

DOI
https://doi.org/10.1039/C3CC44193H
Article type
Communication
Submitted
04 Jun 2013
Accepted
08 Oct 2013
First published
10 Oct 2013

Chem. Commun., 2013,49, 11329-11331

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Modular structure of a robust microporous MOF based on Cu2 paddle-wheels with high CO2 selectivity

J. M. Seco, D. Fairen-Jimenez, A. J. Calahorro, L. Méndez-Liñán, M. Pérez-Mendoza, N. Casati, E. Colacio and A. Rodríguez-Diéguez, Chem. Commun., 2013, 49, 11329 DOI: 10.1039/C3CC44193H

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