Unprecedented infinite lanthanide hydroxide ribbons interconnected by Pra2biim2− (H2Pra2biim = 1′-di(propionic acid)-2,2′-biimidazole) into 3-D [Ln3(μ3-OH)3(Pra2biim)3 (H2O)2]n·4nH2O (Ln = Nd, Pr and La) have been achieved by utilizing the unique H2Pra2biim–Ln3+ hydrolysis system. The Ln⋯Ln antiferromagnetic coupling with magnetic anisotropy has been observed.
![Graphical abstract: Unprecedented infinite lanthanide hydroxide ribbons [Ln3(μ3-OH)3]n6n+ in a 3-D metal–organic framework](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C3CC44181D&imageInfo.ImageIdentifier.Year=2013)
R. Sang and L. Xu, Chem. Commun., 2013, 49, 8344 DOI: 10.1039/C3CC44181D
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