Issue 71, 2013
From the journal:

Chemical Communications

Iodine recycling via 1,3-migration in iodoindoles under metal catalysis†

Benito Alcaide,*a   Pedro Almendros,*b   José M. Alonso,a   Sara Cembellín,a   Israel Fernández,c   Teresa Martínez del Campoa  and  M. Rosario Torresd  

* Corresponding authors

a Grupo de Lactamas y Heterociclos Bioactivos, Departamento de Química Orgánica, Unidad Asociada al CSIC, Facultad de Química, Universidad Complutense de Madrid, 28040-Madrid, Spain
E-mail: alcaideb@quim.ucm.es
Fax: +34 91-3944103

b Instituto de Química Orgánica General, IQOG, CSIC, Juan de la Cierva 3, 28006-Madrid, Spain
E-mail: Palmendros@iqog.csic.es
Fax: +34 91-5644853

c Departamento de Química Orgánica, Facultad de Química, Universidad Complutense de Madrid, 28040-Madrid, Spain

d CAI Difracción de Rayos X, Facultad de Química, Universidad Complutense de Madrid, 28040-Madrid, Spain

Abstract

3-Substituted (indol-2-yl)-α-allenols show divergent patterns of reactivity under metal catalysis. An unprecedented intramolecular 1,3-iodine migration is described.

Graphical abstract: Iodine recycling via 1,3-migration in iodoindoles under metal catalysis

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Article information

DOI
https://doi.org/10.1039/C3CC44073G
Article type
Communication
Submitted
31 May 2013
Accepted
04 Jul 2013
First published
04 Jul 2013

Chem. Commun., 2013,49, 7779-7781

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Iodine recycling via 1,3-migration in iodoindoles under metal catalysis

B. Alcaide, P. Almendros, J. M. Alonso, S. Cembellín, I. Fernández, T. M. del Campo and M. R. Torres, Chem. Commun., 2013, 49, 7779 DOI: 10.1039/C3CC44073G

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