Issue 76, 2013

Metal ion directed metal–organic rotaxane frameworks with intrinsic features of self-penetration and interpenetration

Abstract

Three novel self-catenated 4-connected uninodal (65·8)-mok metal–organic rotaxane frameworks (MORFs) containing cucurbit[6]uril were constructed from the in situ trans/cis-configuration (1 : 1) of rotaxanes by taking advantage of a d10 metal ion directed synthesis. It was revealed that the effect of hydrogen bonds and π–π stacking interactions play significant roles in the self-assembly process.

Graphical abstract: Metal ion directed metal–organic rotaxane frameworks with intrinsic features of self-penetration and interpenetration

Supplementary files

Article information

Article type
Communication
Submitted
27 May 2013
Accepted
30 Jul 2013
First published
31 Jul 2013

Chem. Commun., 2013,49, 8555-8557

Metal ion directed metal–organic rotaxane frameworks with intrinsic features of self-penetration and interpenetration

J. Liang, X. Wang, Y. Jiao, C. Qin, K. Shao, Z. Su and Q. Wu, Chem. Commun., 2013, 49, 8555 DOI: 10.1039/C3CC43990A

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