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Issue 75, 2013
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Sulfonylcarbamate as a versatile and unique hydroxy-protecting group: a protecting group stable under severe conditions and labile under mild conditions

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Abstract

The sulfonylcarbamate group is a unique hydroxyl protecting group. In contrast to typical acyl protecting groups, the sulfonylcarbamate group is stable under harsh basic conditions, while showing labile behavior under mild basic conditions. Its compatibility with other hydroxyl protecting groups and application to carbohydrate chemistry is demonstrated.

Graphical abstract: Sulfonylcarbamate as a versatile and unique hydroxy-protecting group: a protecting group stable under severe conditions and labile under mild conditions

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Publication details

The article was received on 27 May 2013, accepted on 24 Jul 2013 and first published on 25 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC43968B
Citation: Chem. Commun., 2013,49, 8332-8334
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    Sulfonylcarbamate as a versatile and unique hydroxy-protecting group: a protecting group stable under severe conditions and labile under mild conditions

    S. Manabe, M. Yamaguchi and Y. Ito, Chem. Commun., 2013, 49, 8332
    DOI: 10.1039/C3CC43968B

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