Issue 79, 2013

Nitrous oxide reduction-coupled alkene–alkene coupling catalysed by metalloporphyrins

Abstract

Porphyrin complexes of iron, manganese and cobalt catalysed reductive dimerization of alkenes with NaBH4 under N2O. The reaction system using FeIII porphyrin generated an FeI porphyrin intermediate that reduced N2O to regenerate FeIII porphyrin.

Graphical abstract: Nitrous oxide reduction-coupled alkene–alkene coupling catalysed by metalloporphyrins

Supplementary files

Article information

Article type
Communication
Submitted
24 May 2013
Accepted
04 Aug 2013
First published
05 Aug 2013

Chem. Commun., 2013,49, 8979-8981

Nitrous oxide reduction-coupled alkenealkene coupling catalysed by metalloporphyrins

S. Saito, H. Ohtake, N. Umezawa, Y. Kobayashi, N. Kato, M. Hirobe and T. Higuchi, Chem. Commun., 2013, 49, 8979 DOI: 10.1039/C3CC43912G

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