Issue 72, 2013

Perfluorocyclohexene bridges in inverse DiArylEthenes: synthesis through Pd-catalysed C–H bond activation, experimental and theoretical studies on their photoreactivity

Abstract

The palladium-catalysed direct di-heteroarylation of 1,2-dichloroperfluorocyclohexene with a variety of heteroarenes gives rise in to a new family of 1,2-di(heteroaryl)perfluorocyclohexenes. These derivatives do not exhibit photoreactivity and this unexpected outcome is explained by calculations demonstrating the lack of reactive isomers.

Graphical abstract: Perfluorocyclohexene bridges in inverse DiArylEthenes: synthesis through Pd-catalysed C–H bond activation, experimental and theoretical studies on their photoreactivity

Supplementary files

Article information

Article type
Communication
Submitted
18 May 2013
Accepted
09 Jul 2013
First published
09 Jul 2013

Chem. Commun., 2013,49, 7896-7898

Perfluorocyclohexene bridges in inverse DiArylEthenes: synthesis through Pd-catalysed C–H bond activation, experimental and theoretical studies on their photoreactivity

K. Yuan, J. Boixel, H. Le Bozec, A. Boucekkine, H. Doucet, V. Guerchais and D. Jacquemin, Chem. Commun., 2013, 49, 7896 DOI: 10.1039/C3CC43754J

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