Issue 56, 2013

Isostructural salts of the same complex showing contrasting thermal spin-crossover mediated by multiple phase changes

Abstract

Two salts of [FeL2]2+ (L = 2,6-bis[5-methyl-1H-pyrazol-3-yl]pyridine) are isostructural under ambient conditions but show different thermal spin-crossover behaviour, involving a variety of crystallographic phase changes.

Graphical abstract: Isostructural salts of the same complex showing contrasting thermal spin-crossover mediated by multiple phase changes

Supplementary files

Article information

Article type
Communication
Submitted
14 May 2013
Accepted
29 May 2013
First published
30 May 2013
This article is Open Access

Chem. Commun., 2013,49, 6280-6282

Isostructural salts of the same complex showing contrasting thermal spin-crossover mediated by multiple phase changes

T. D. Roberts, M. A. Little, F. Tuna, C. A. Kilner and M. A. Halcrow, Chem. Commun., 2013, 49, 6280 DOI: 10.1039/C3CC43613F

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