A novel efficient method for the synthesis of substituted olefins; cross coupling of two different alcohols using NaHSO4/SiO2

Tadashi Aoyama; Shuichi Koda; Yuka Takeyoshi; Tetsuhiro Ito; Toshio Takido; Mitsuo Kodomari

doi:10.1039/C3CC42746C

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A novel efficient method for the synthesis of substituted olefins; cross coupling of two different alcohols using NaHSO₄/SiO₂†

Tadashi Aoyama,*^a Shuichi Koda,^a Yuka Takeyoshi,^a Tetsuhiro Ito,^a Toshio Takido^a and Mitsuo Kodomari^b

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* Corresponding authors

^a Department of Materials and Applied Chemistry, College of Science and Technology, Nihon University, Kanda Surugadai, Chiyoda-ku, Tokyo, Japan
E-mail: aoyama.tadashi@nihon-u.ac.jp
Fax: +81 3 3259 0818
Tel: +81 3 3259 0818

^b The Institute of Natural Sciences, College of Humanities and Science, Nihon University, Japan
Tel: +81 3 53179366

Abstract

Simple and efficient cross coupling of alcohols was developed in the presence of NaHSO₄/SiO₂ to give the corresponding substituted olefins. Direct coupling of alcohols and alkenes was also achieved to give substituted olefins. NaHSO₄/SiO₂ could be recycled 7 times without loss of catalytic activity.

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Article information

DOI: https://doi.org/10.1039/C3CC42746C
Article type: Communication
Submitted: 15 Apr 2013
Accepted: 01 Jun 2013
First published: 04 Jun 2013

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Chem. Commun., 2013,49, 6605-6607

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A novel efficient method for the synthesis of substituted olefins; cross coupling of two different alcohols using NaHSO₄/SiO₂

T. Aoyama, S. Koda, Y. Takeyoshi, T. Ito, T. Takido and M. Kodomari, Chem. Commun., 2013, 49, 6605 DOI: 10.1039/C3CC42746C

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Chemical Communications