Issue 57, 2013

Application of chiral N-tert-butylsulfinyl vinyl aziridines in Rh(i) catalyzed 1,4-addition of aryl boronic acids to cyclic enones

Abstract

Chiral N-tert-butylsulfinyl vinyl aziridine ligands prepared from a readily available (R)-tert-butanesulfinamide have been applied in the rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to cyclic enones, which gives high yields and excellent enantioselectivities.

Graphical abstract: Application of chiral N-tert-butylsulfinyl vinyl aziridines in Rh(i) catalyzed 1,4-addition of aryl boronic acids to cyclic enones

Supplementary files

Article information

Article type
Communication
Submitted
12 Apr 2013
Accepted
29 May 2013
First published
30 May 2013

Chem. Commun., 2013,49, 6433-6435

Application of chiral N-tert-butylsulfinyl vinyl aziridines in Rh(I) catalyzed 1,4-addition of aryl boronic acids to cyclic enones

Q. Chen, C. Chen, F. Guo and W. Xia, Chem. Commun., 2013, 49, 6433 DOI: 10.1039/C3CC42673D

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