Issue 46, 2013
From the journal:

Chemical Communications

Salt metathesis in three dimensional metal–organic frameworks (MOFs) with unprecedented hydrolytic regenerability†

Tanay Kundu,a   Subash C. Sahoo,a   Subhadeep Sahaa  and  Rahul Banerjee*a  

* Corresponding authors

a Physical/Materials Chemistry Division, CSIR-National Chemical Laboratory, Dr Homi Bhabha Road, Pune-411008, India
E-mail: r.banerjee@ncl.res.in
Fax: +91-20-25902636
Tel: +91-20-25902535

Abstract

Eight Zn-based porous (1.2 nm) homochiral MOFs (ValZnX, AlaZnX, X = Cl−, Br−, HCO2− and CH3CO2−) were synthesized which possess extremely rare zeolitic (unh) topology. These MOFs show an unprecedented hydrolytic regenerability. Salt metathesis reaction performed on these 3D MOFs in water resulted in 2D coordination polymers (CPs).

Graphical abstract: Salt metathesis in three dimensional metal–organic frameworks (MOFs) with unprecedented hydrolytic regenerability

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Article information

DOI
https://doi.org/10.1039/C3CC41842A
Article type
Communication
Submitted
12 Mar 2013
Accepted
18 Apr 2013
First published
19 Apr 2013

Chem. Commun., 2013,49, 5262-5264

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Salt metathesis in three dimensional metal–organic frameworks (MOFs) with unprecedented hydrolytic regenerability

T. Kundu, S. C. Sahoo, S. Saha and R. Banerjee, Chem. Commun., 2013, 49, 5262 DOI: 10.1039/C3CC41842A

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