Issue 43, 2013
From the journal:

Chemical Communications

Guided supramolecular polymerization of oligo(p-phenylenevinylene) functionalized bismelamines†

Mitsuaki Yamauchi,a   Shun Kubota,a   Takashi Karatsu,a   Akihide Kitamura,a   Ayyappanpillai Ajayaghoshb  and  Shiki Yagai*a  

* Corresponding authors

a Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan
E-mail: yagai@faculty.chiba-u.jp
Fax: +81 (0)43-290-3039
Tel: +81 (0)43-290-3368

b Photosciences and Photonics Group, Chemical Sciences and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology (CSIR-NIIST), Trivandrum-695019, India

Abstract

Bismelamines end-functionalized with oligo(p-phenylenevinylene) self-aggregate in nonpolar solvent to form short nanorods by helical π–π stacking. This inherent self-aggregation can be guided to a supramolecular polymerization pathway by complexing with a cyanurate, leading to gel-forming elongated nanotapes lacking the helical sense of the π-conjugated moieties.

Graphical abstract: Guided supramolecular polymerization of oligo(p-phenylenevinylene) functionalized bismelamines

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Article information

DOI
https://doi.org/10.1039/C3CC41461B
Article type
Communication
Submitted
26 Feb 2013
Accepted
04 Apr 2013
First published
05 Apr 2013

Chem. Commun., 2013,49, 4941-4943

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Guided supramolecular polymerization of oligo(p-phenylenevinylene) functionalized bismelamines

M. Yamauchi, S. Kubota, T. Karatsu, A. Kitamura, A. Ajayaghosh and S. Yagai, Chem. Commun., 2013, 49, 4941 DOI: 10.1039/C3CC41461B

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