Issue 45, 2013

Is Y2(B12H12)3 the main intermediate in the decomposition process of Y(BH4)3?

Abstract

Dodecaborates, i.e. the [B12H12]2− containing species, are often observed as main intermediates in the hydrogen sorption cycle of metal borohydrides, hindering rehydrogenation. In the decomposition process of Y(BH4)3, yttrium octahydrotriborate, i.e. Y(B3H8)3, rather than the stable Y2(B12H12)3, is formed as the main intermediate.

Graphical abstract: Is Y2(B12H12)3 the main intermediate in the decomposition process of Y(BH4)3?

Supplementary files

Article information

Article type
Communication
Submitted
13 Feb 2013
Accepted
11 Apr 2013
First published
17 Apr 2013
This article is Open Access
Creative Commons BY license

Chem. Commun., 2013,49, 5234-5236

Is Y2(B12H12)3 the main intermediate in the decomposition process of Y(BH4)3?

Y. Yan, A. Remhof, D. Rentsch, Y. Lee, Y. Whan Cho and A. Züttel, Chem. Commun., 2013, 49, 5234 DOI: 10.1039/C3CC41184B

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