Issue 33, 2013
From the journal:

Chemical Communications

Synthesis and characterisation of a lanthanide-capped dodecavanadate cage†

Jamie M. Cameron,a   Graham N. Newton,b   Christoph Busche,a   De-Liang Long,a   Hiroki Oshiob  and  Leroy Cronin*a  

* Corresponding authors

a WestCHEM, School of Chemistry, The University of Glasgow, Glasgow, UK
E-mail: L.Cronin@chem.gla.ac.uk
Web: http://www.croninlab.com
Fax: +44 (0)141-330-4888
Tel: +44 (0)141-330-6650

b Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba 305-8571, Japan

Abstract

The synthesis of a series of discrete lanthanide-capped polyoxovanadate cages is presented along with magnetic and electrochemical measurements which reveal a redox active dodecavanadate cluster with potential as a new functional building unit in polyoxovanadate chemistry.

Graphical abstract: Synthesis and characterisation of a lanthanide-capped dodecavanadate cage

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Article information

DOI
https://doi.org/10.1039/C3CC40912K
Article type
Communication
Submitted
03 Feb 2013
Accepted
04 Mar 2013
First published
05 Mar 2013

Chem. Commun., 2013,49, 3395-3397

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Synthesis and characterisation of a lanthanide-capped dodecavanadate cage

J. M. Cameron, G. N. Newton, C. Busche, D. Long, H. Oshio and L. Cronin, Chem. Commun., 2013, 49, 3395 DOI: 10.1039/C3CC40912K

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