Issue 29, 2013
From the journal:

Chemical Communications

π-Complexes from acyl cyanides and lithium dimethylcuprate(i)†

Steven H. Bertz,*a   Richard A. Hardin,a   Michael D. Murphya  and  Craig A. Ogle*a  

* Corresponding authors

a Department of Chemistry, University of North Carolina at Charlotte, Charlotte, NC 28223, USA
E-mail: sbertz1@uncc.edu, cogle@uncc.edu

Abstract

Rapid injection of pyruvonitrile or benzoyl cyanide into solutions of Me2CuLi in THF-d8 at −100 °C gave complexes that were stable at this temperature. 1D NMR with multiply labelled substrates (13C/15N) and 2D NMR (1H/13C) identified them as the first cuprate–carbonyl π-complexes.

Graphical abstract: π-Complexes from acyl cyanides and lithium dimethylcuprate(i)

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC40602D
Article type
Communication
Submitted
24 Jan 2013
Accepted
25 Feb 2013
First published
05 Mar 2013

Chem. Commun., 2013,49, 3010-3012

Permissions

Request permissions

π-Complexes from acyl cyanides and lithium dimethylcuprate(I)

S. H. Bertz, R. A. Hardin, M. D. Murphy and C. A. Ogle, Chem. Commun., 2013, 49, 3010 DOI: 10.1039/C3CC40602D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements