Issue 35, 2013
From the journal:

Chemical Communications

Hydrogen-bond-driven ‘homogeneous intercalation’ for rapid, reversible, and ultra-precise actuation of layered clay nanosheets†

Shinsuke Ishihara,*a   Nobuo Iyi,*b   Yoshihiro Tsujimoto,b   Satoshi Tominaka,a   Yoshitaka Matsushita,b   Venkata Krishnan,a   Misaho Akada,a   Jan Labuta,a   Kenzo Deguchi,c   Shinobu Ohki,c   Masataka Tansho,c   Tadashi Shimizu,c   Qingmin Ji,a   Yusuke Yamauchi,a   Jonathan P. Hill,ad   Hideki Abeb  and  Katsuhiko Ariga*ad  

* Corresponding authors

a International Center for Materials Nanoarchitectonics, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan
E-mail: ISHIHARA.Shinsuke@nims.go.jp, ARIGA.Katsuhiko@nims.go.jp

b National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan
E-mail: IYI.Nobuo@nims.go.jp

c High Field NMR Group, National Institute for Materials Science, 3-13 Sakura, Tsukuba, Ibaraki 305-0003, Japan

d JST-CREST, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan

Abstract

The use of hydrogen bonds permits a fluidic motion of differently sized alcohol molecules across the interlayer gap in LDH, which enables rapid and reversible tuning of interlayer spacing of the LDH at sub-Ångström precision by changing the mole ratio of the different alcohols.

Graphical abstract: Hydrogen-bond-driven ‘homogeneous intercalation’ for rapid, reversible, and ultra-precise actuation of layered clay nanosheets

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Article information

DOI
https://doi.org/10.1039/C3CC40398J
Article type
Communication
Submitted
17 Jan 2013
Accepted
11 Feb 2013
First published
13 Feb 2013

Chem. Commun., 2013,49, 3631-3633

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Hydrogen-bond-driven ‘homogeneous intercalation’ for rapid, reversible, and ultra-precise actuation of layered clay nanosheets

S. Ishihara, N. Iyi, Y. Tsujimoto, S. Tominaka, Y. Matsushita, V. Krishnan, M. Akada, J. Labuta, K. Deguchi, S. Ohki, M. Tansho, T. Shimizu, Q. Ji, Y. Yamauchi, J. P. Hill, H. Abe and K. Ariga, Chem. Commun., 2013, 49, 3631 DOI: 10.1039/C3CC40398J

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