Issue 22, 2013

Fluorinated 5- and 7-membered carbacycle motifs by reaction of difluorocarbene with acetylene ethers

Abstract

The reaction of acetylene ethers with difluorocarbene (CF2), generated from the Ruppert–Prakash reagent, unexpectedly gave rise to co-produced fluorinated bicyclic [2.1.1]-hex-2-ene and cyclohepta-1,4-diene ring products.

Graphical abstract: Fluorinated 5- and 7-membered carbacycle motifs by reaction of difluorocarbene with acetylene ethers

Supplementary files

Article information

Article type
Communication
Submitted
19 Dec 2012
Accepted
25 Jan 2013
First published
28 Jan 2013

Chem. Commun., 2013,49, 2189-2191

Fluorinated 5- and 7-membered carbacycle motifs by reaction of difluorocarbene with acetylene ethers

P. W. Chia, D. Bello, A. M. Z. Slawin and D. O'Hagan, Chem. Commun., 2013, 49, 2189 DOI: 10.1039/C3CC39066G

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