Issue 21, 2013
From the journal:

Chemical Communications

Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials†

Qianlong Wang,a   Alex Madsen,b   John R. Owenb  and  Mark T. Weller*a  

* Corresponding authors

a Department of Chemistry, University of Bath, Bath, UK
E-mail: m.t.weller@bath.ac.uk

b School of Chemistry, University of Southampton, UK

Abstract

Synthesis under hydrofluorothermal conditions produces new iron, manganese and vanadium fluorosulfates; these include the isomorphous Na3MIIIF2(SO4)2, M = V, Mn, Fe, with a sheet-like structure formed of linked MIIIF2O4 and SO4 polyhedra separated by sodium ions which may be extracted electrochemically at potentials of >3.5 V.

Graphical abstract: Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials

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Article information

DOI
https://doi.org/10.1039/C3CC38897B
Article type
Communication
Submitted
23 Jul 2012
Accepted
01 Feb 2013
First published
04 Feb 2013

Chem. Commun., 2013,49, 2121-2123

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Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials

Q. Wang, A. Madsen, J. R. Owen and M. T. Weller, Chem. Commun., 2013, 49, 2121 DOI: 10.1039/C3CC38897B

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