Issue 22, 2013

P–P bond formation via reductive dimerization of [Cp*Fe(η5-P5)] by divalent samarocenes

Abstract

The two new 3d/4f polyphosphide complexes [(Cp*Fe)2P10{Sm(η5-C5Me4R)2}2] (Cp* = η5-C5Me5; R = Me, nPr) were prepared by reductive dimerization of [Cp*Fe(η5-P5)] with samarocenes. They are the first P10 bridging 3d/4f metal complexes and the first examples of reductive coupling of polyphosphide complexes by divalent lanthanides.

Graphical abstract: P–P bond formation via reductive dimerization of [Cp*Fe(η5-P5)] by divalent samarocenes

Supplementary files

Article information

Article type
Communication
Submitted
10 Dec 2012
Accepted
18 Jan 2013
First published
05 Feb 2013

Chem. Commun., 2013,49, 2183-2185

P–P bond formation via reductive dimerization of [Cp*Fe(η5-P5)] by divalent samarocenes

T. Li, M. T. Gamer, M. Scheer, S. N. Konchenko and P. W. Roesky, Chem. Commun., 2013, 49, 2183 DOI: 10.1039/C3CC38841G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements