Issue 20, 2013
From the journal:

Chemical Communications

Organocatalytic asymmetric synthesis of 3,3-disubstituted oxindoles featuring two heteroatoms at the C3 position†

Feng Zhou,a   Xing-Ping Zeng,a   Chao Wang,a   Xiao-Li Zhaoa  and  Jian Zhou*a  

* Corresponding authors

a Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 N. Zhongshan Road, Shanghai, P. R. China
E-mail: jzhou@chem.ecnu.edu.cn
Fax: +86 21-6223-4560
Tel: +86 21-6223-4560

Abstract

We report the first organocatalytic asymmetric synthesis of 3,3-disubstituted oxindoles featuring two heteroatoms at the C3 position. Importantly, 3-thiooxindoles and 3-alkoxyoxindoles are demonstrated to be reactive nucleophiles for the development of catalytic asymmetric reactions for the first time.

Graphical abstract: Organocatalytic asymmetric synthesis of 3,3-disubstituted oxindoles featuring two heteroatoms at the C3 position

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Article information

DOI
https://doi.org/10.1039/C3CC38819K
Article type
Communication
Submitted
09 Dec 2012
Accepted
19 Jan 2013
First published
23 Jan 2013

Chem. Commun., 2013,49, 2022-2024

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Organocatalytic asymmetric synthesis of 3,3-disubstituted oxindoles featuring two heteroatoms at the C3 position

F. Zhou, X. Zeng, C. Wang, X. Zhao and J. Zhou, Chem. Commun., 2013, 49, 2022 DOI: 10.1039/C3CC38819K

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