Issue 22, 2013
From the journal:

Chemical Communications

Fluorine interaction controlled AIEE phenomenon in an expanded calixbenzophyrin and its vapoluminescent response: turn on emission with volatile ketones and esters†

P. S. Salini,a   M. G. Derry Holaday,a   M. L. P. Reddy,b   C. H. Suresh*b  and  A. Srinivasan*c  

* Corresponding authors

a Photosciences and Photonics Group, Chemical Sciences and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology (NIIST), Trivandrum 695 019, Kerala, India

b Inorganic Chemistry Section, Chemical Sciences and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology (NIIST), Trivandrum 695 019, Kerala, India

c School of Chemical Sciences, National Institute of Science Education and Research, IOP Campus, Sainik School – P. O., Bhubaneswar – 751 005, Odisha, India
E-mail: srini@niser.ac.in
Fax: +91 674-2302436

Abstract

Fluorine interaction assisted AIEE characteristic in an expanded calixbenzophyrin is presented by single-crystal X-ray-diffraction analysis and molecular modelling approaches. Selective exposure to volatile organic compounds such as ketones and esters results in the breaking of fluorine interaction, leading to enhanced monomer emission.

Graphical abstract: Fluorine interaction controlled AIEE phenomenon in an expanded calixbenzophyrin and its vapoluminescent response: turn on emission with volatile ketones and esters

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Article information

DOI
https://doi.org/10.1039/C3CC38723B
Article type
Communication
Submitted
05 Dec 2012
Accepted
23 Jan 2013
First published
23 Jan 2013

Chem. Commun., 2013,49, 2213-2215

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Fluorine interaction controlled AIEE phenomenon in an expanded calixbenzophyrin and its vapoluminescent response: turn on emission with volatile ketones and esters

P. S. Salini, M. G. Derry Holaday, M. L. P. Reddy, C. H. Suresh and A. Srinivasan, Chem. Commun., 2013, 49, 2213 DOI: 10.1039/C3CC38723B

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