Issue 22, 2013
From the journal:

Chemical Communications

Syntheses and crystal structures of neutral tetrairon complexes with the unique SCPPh2S ligand†

Yao-Cheng Shi*a  and  Fei Gua  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
E-mail: ycshi@yzu.edu.cn
Fax: +86-0514-87857939
Tel: +86-0514-87857939

Abstract

The novel reactions of cluster salts [(μ-RS)Fe2(CO)6(μ4-CS2)Fe2(CO)6][Et3NH] with Ph2PCl, via the insertion of the PPh2 group into an activated C–S bond, afford the unprecedented tetrairon complexes with the unique SCPPh2S ligand which is coordinated to (μ-RS)Fe2(CO)6 and Fe2(CO)6 units in a μ4-k2C:k4S,S′ mode (R = Ph, CH3O2CCH2).

Graphical abstract: Syntheses and crystal structures of neutral tetrairon complexes with the unique SCPPh2S ligand

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Article information

DOI
https://doi.org/10.1039/C3CC00169E
Article type
Communication
Submitted
02 Dec 2012
Accepted
21 Jan 2013
First published
23 Jan 2013

Chem. Commun., 2013,49, 2255-2257

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Syntheses and crystal structures of neutral tetrairon complexes with the unique SCPPh2S ligand

Y. Shi and F. Gu, Chem. Commun., 2013, 49, 2255 DOI: 10.1039/C3CC00169E

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