Issue 13, 2013
From the journal:

Chemical Communications

Gold-catalysed tuning of reactivity in allenes: 9-endo hydroarylation versus formal 5-exo hydroalkylation†

Benito Alcaide,*a   Pedro Almendros,*b   Sara Cembellín,a   Teresa Martínez del Campoa  and  Israel Fernándezc  

* Corresponding authors

a Grupo de Lactamas y Heterociclos Bioactivos, Departamento de Química Orgánica, Unidad Asociada al CSIC, Facultad de Química, Universidad Complutense de Madrid, 28040-Madrid, Spain
E-mail: alcaideb@quim.ucm.es
Fax: +34 91-3944103

b Instituto de Química Orgánica General, IQOG, CSIC, Juan de la Cierva 3, 28006-Madrid, Spain
E-mail: Palmendros@iqog.csic.es
Fax: +34 91-5644853

c Departamento de Química Orgánica, Facultad de Química, Universidad Complutense de Madrid, 28040-Madrid, Spain

Abstract

The divergent gold-catalysed reactivity (Csp2–H versus Csp3–H) of aryloxy-tethered allenes has been uncovered.

Graphical abstract: Gold-catalysed tuning of reactivity in allenes: 9-endo hydroarylation versus formal 5-exo hydroalkylation

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Article information

DOI
https://doi.org/10.1039/C2CC37872H
Article type
Communication
Submitted
30 Oct 2012
Accepted
19 Dec 2012
First published
19 Dec 2012

Chem. Commun., 2013,49, 1282-1284

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Gold-catalysed tuning of reactivity in allenes: 9-endo hydroarylation versus formal 5-exo hydroalkylation

B. Alcaide, P. Almendros, S. Cembellín, T. M. D. Campo and I. Fernández, Chem. Commun., 2013, 49, 1282 DOI: 10.1039/C2CC37872H

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