Issue 12, 2013
From the journal:

Chemical Communications

A dinuclear alkynylplatinum(ii) pyridinedicarboxamide: conformational change-induced switching of emission properties†

Annika Gross,a   Toshiyuki Moriuchi*a  and  Toshikazu Hirao*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan
E-mail: moriuchi@chem.eng.osaka-u.ac.jp, hirao@chem.eng.osaka-u.ac.jp
Fax: +81-6-6879-7415
Tel: +81-6-6879-7413

Abstract

The synthesis and characterisation of a dinuclear pyridinedicarboxamide–platinum(II) complex exhibiting tunable optical properties based on metal–metal interaction are reported. Conformational change-induced switching between metal-to-ligand charge-transfer and metal–metal-to-ligand charge-transfer emission properties by the influence of methanol was demonstrated.

Graphical abstract: A dinuclear alkynylplatinum(ii) pyridinedicarboxamide: conformational change-induced switching of emission properties

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Article information

DOI
https://doi.org/10.1039/C2CC37706C
Article type
Communication
Submitted
23 Oct 2012
Accepted
04 Dec 2012
First published
06 Dec 2012

Chem. Commun., 2013,49, 1163-1165

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A dinuclear alkynylplatinum(II) pyridinedicarboxamide: conformational change-induced switching of emission properties

A. Gross, T. Moriuchi and T. Hirao, Chem. Commun., 2013, 49, 1163 DOI: 10.1039/C2CC37706C

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