Issue 8, 2013

Synthesis and characterisation of the unsubstituted dipyrrin and 4,4-dichloro-4-bora-3a,4a-diaza-s-indacene: improved synthesis and functionalisation of the simplest BODIPY framework

Abstract

An improved and scalable synthesis of the unsubstituted 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene framework facilitates access to the previously unreported parent dipyrrin HCl salt, as well as 4,4-dichloro-4-bora-3a,4a-diaza-s-indacene.

Graphical abstract: Synthesis and characterisation of the unsubstituted dipyrrin and 4,4-dichloro-4-bora-3a,4a-diaza-s-indacene: improved synthesis and functionalisation of the simplest BODIPY framework

Supplementary files

Article information

Article type
Communication
Submitted
13 Oct 2012
Accepted
14 Nov 2012
First published
13 Dec 2012

Chem. Commun., 2013,49, 816-818

Synthesis and characterisation of the unsubstituted dipyrrin and 4,4-dichloro-4-bora-3a,4a-diaza-s-indacene: improved synthesis and functionalisation of the simplest BODIPY framework

B. R. Groves, S. M. Crawford, T. Lundrigan, C. F. Matta, S. Sowlati-Hashjin and A. Thompson, Chem. Commun., 2013, 49, 816 DOI: 10.1039/C2CC37480C

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