Issue 3, 2013
From the journal:

Chemical Communications

Photostability of a dyad of magnesium porphyrin and fullerene and its application to photocurrent conversion†

Takahiko Ichiki,a   Yutaka Matsuo*a  and  Eiichi Nakamura*a  

* Corresponding authors

a Department of Chemistry, School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
E-mail: matsuo@chem.s.u-tokyo.ac.jp, nakamura@chem.s.u-tokyo.ac.jp
Fax: +81 3-5800-6889

Abstract

A new type of acceptor–donor2 dyad system containing two magnesium porphyrin molecules and a fullerene molecule is much more stable than the magnesium porphyrin itself. When it is fabricated into a binary system using imidazole carboxylic acid as a linker to indium tin oxide, the molecule effects efficient photocurrent generation that surpasses the device using the corresponding zinc porphyrin.

Graphical abstract: Photostability of a dyad of magnesium porphyrin and fullerene and its application to photocurrent conversion

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Article information

DOI
https://doi.org/10.1039/C2CC36988E
Article type
Communication
Submitted
26 Sep 2012
Accepted
08 Nov 2012
First published
08 Nov 2012

Chem. Commun., 2013,49, 279-281

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Photostability of a dyad of magnesium porphyrin and fullerene and its application to photocurrent conversion

T. Ichiki, Y. Matsuo and E. Nakamura, Chem. Commun., 2013, 49, 279 DOI: 10.1039/C2CC36988E

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