Issue 39, 2013
From the journal:

Chemical Communications

[Cu30I16(mtpmt)12(μ10-S4)]: an unusual 30-membered copper(i) cluster derived from the C–S bond cleavage and its use in heterogeneous catalysis†‡

Hong-Xi Li,*a   Wei Zhao,a   Hai-Yan Li,a   Zhong-Lin Xu,a   Wen-Xia Wanga  and  Jian-Ping Lang*ab  

* Corresponding authors

a College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 RenAi Road, Suzhou 215123, Jiangsu, P. R. China
E-mail: jplang@suda.edu.cn, lihx@suda.edu.cn
Fax: +86 512 65880089

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 210032, P. R. China

Abstract

The Cu(I)-mediated C–S bond cleavage of 5-methyl-4-(p-tolyl)pyrimidine-2-thiol (mtpmtH) gave one 30-nuclear cluster [Cu30I16(mtpmt)12(μ10-S4)], one polymeric complex [(bmtpms)Cu-(μ-I)]n and one tetranuclear complex [(bmptmds){Cu(μ-I)}2]2; the 30-nuclear cluster displayed excellent catalytic performances in the coupling reactions of N-heterocycles and arylboronic acids and could be recycled and reused.

Graphical abstract: [Cu30I16(mtpmt)12(μ10-S4)]: an unusual 30-membered copper(i) cluster derived from the C–S bond cleavage and its use in heterogeneous catalysis

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Article information

DOI
https://doi.org/10.1039/C2CC36736J
Article type
Communication
Submitted
12 Aug 2012
Accepted
11 Oct 2012
First published
19 Oct 2012

Chem. Commun., 2013,49, 4259-4261

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[Cu30I16(mtpmt)12(μ10-S4)]: an unusual 30-membered copper(I) cluster derived from the C–S bond cleavage and its use in heterogeneous catalysis

H. Li, W. Zhao, H. Li, Z. Xu, W. Wang and J. Lang, Chem. Commun., 2013, 49, 4259 DOI: 10.1039/C2CC36736J

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