Issue 39, 2013

The efficient desymmetrization of glycerol using scaffolding catalysis

Abstract

Glycerol is an ideal building block for the synthesis of complex molecules, because it is inexpensive and highly functionalized. We report the desymmetrization of glycerol through silyl transfer, using a chiral organic catalyst in high yield and enantioselectivity.

Graphical abstract: The efficient desymmetrization of glycerol using scaffolding catalysis

Supplementary files

Article information

Article type
Communication
Submitted
20 May 2012
Accepted
27 Jun 2012
First published
13 Jul 2012

Chem. Commun., 2013,49, 4370-4372

The efficient desymmetrization of glycerol using scaffolding catalysis

Z. X. Giustra and K. L. Tan, Chem. Commun., 2013, 49, 4370 DOI: 10.1039/C2CC33633B

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