Issue 93, 2012
From the journal:

Chemical Communications

1,5-Migration of rhodium via C–H bond activation in catalytic decyanative silylation of nitriles†

Mamoru Tobisu,*a   Junya Hasegawa,b   Yusuke Kita,b   Hirotaka Kinutab  and  Naoto Chatani*b  

* Corresponding authors

a Center for Atomic and Molecular Technologies, Graduate School of Engineering, Osaka University, Suita, Japan
E-mail: tobisu@chem.eng.osaka-u.ac.jp

b Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Japan
E-mail: chatani@chem.eng.osaka-u.ac.jp

Abstract

Unprecedented aryl-to-aryl 1,5-rhodium migration is involved in decyanative silylation of aryl cyanides bearing a tethered arene. The 1,5-migration proceeds through remote C–H bond activation. 1,5-Migration also occurs in other rhodium-catalyzed reactions, including borylation and oxidative Mizoroki–Heck reactions.

Graphical abstract: 1,5-Migration of rhodium via C–H bond activation in catalytic decyanative silylation of nitriles

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Article information

DOI
https://doi.org/10.1039/C2CC36601K
Article type
Communication
Submitted
11 Sep 2012
Accepted
10 Oct 2012
First published
11 Oct 2012

Chem. Commun., 2012,48, 11437-11439

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1,5-Migration of rhodium via C–H bond activation in catalytic decyanative silylation of nitriles

M. Tobisu, J. Hasegawa, Y. Kita, H. Kinuta and N. Chatani, Chem. Commun., 2012, 48, 11437 DOI: 10.1039/C2CC36601K

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