Issue 99, 2012
From the journal:

Chemical Communications

Overcoming the solvation shell during the crystallisation of diatrizoic acid from dimethylsulfoxide†

Katharina Fucke,a   Judith A. K. Howarda  and  Jonathan W. Steed*a  

* Corresponding authors

a Durham University, South Road, Durham DH1 3LE, UK
E-mail: Jon.Steed@durham.ac.uk
Fax: +44 (0)191 384 4737
Tel: +44 (0)191 334 2085

Abstract

We present three crystal structures of diatrizoic acid (DTA) DMSO solvates illustrating progressive desolvation of the DTA molecule and concomitant increasing degree of DTA self-association. Using these structures, plausible pathways for overcoming the solvation shell of DTA during its crystallisation from solution are discussed.

Graphical abstract: Overcoming the solvation shell during the crystallisation of diatrizoic acid from dimethylsulfoxide

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Article information

DOI
https://doi.org/10.1039/C2CC35995B
Article type
Communication
Submitted
18 Aug 2012
Accepted
25 Oct 2012
First published
26 Oct 2012

Chem. Commun., 2012,48, 12065-12067

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Overcoming the solvation shell during the crystallisation of diatrizoic acid from dimethylsulfoxide

K. Fucke, J. A. K. Howard and J. W. Steed, Chem. Commun., 2012, 48, 12065 DOI: 10.1039/C2CC35995B

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