Issue 84, 2012
From the journal:

Chemical Communications

Phosphine–alkeneligand-mediated alkyl–alkyl and alkyl–halide elimination processes from palladium(ii)†

Luke Tuxworth,ab   Lise Baiget,ab   Andreas Phanopoulos,b   Owen J. Metters,b   Andrei S. Batsanov,b   Mark A. Fox,ab   Judith A. K. Howardb  and  Philip W. Dyer*ab  

* Corresponding authors

a Centre for Sustainable Chemical Processes, Department of Chemistry, Durham University, South Road, Durham, UK
E-mail: p.w.dyer@durham.ac.uk
Fax: +44 (0)191 334 2150
Tel: +44 (0)191 384 4737

b Department of Chemistry, Durham University, South Road, Durham, UK

Abstract

N-Diphenylphosphino-7-aza-benzobicyclo[2.2.1]hept-2-ene (2) behaves as a chelating phosphine–alkene ligand for Pd0 and PdII, promoting direct alkyl–alkyl and indirect alkyl–halide reductive elimination reactions due to the stabilisation of the resulting bis(phosphine–alkene)Pd0 complex.

Graphical abstract: Phosphine–alkene ligand-mediated alkyl–alkyl and alkyl–halide elimination processes from palladium(ii)

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Article information

DOI
https://doi.org/10.1039/C2CC35623F
Article type
Communication
Submitted
02 Aug 2012
Accepted
31 Aug 2012
First published
31 Aug 2012

Chem. Commun., 2012,48, 10413-10415

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Phosphine–alkene ligand-mediated alkyl–alkyl and alkyl–halide elimination processes from palladium(II)

L. Tuxworth, L. Baiget, A. Phanopoulos, O. J. Metters, A. S. Batsanov, M. A. Fox, J. A. K. Howard and P. W. Dyer, Chem. Commun., 2012, 48, 10413 DOI: 10.1039/C2CC35623F

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