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Issue 84, 2012
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Preventing thermolysis: precursor design for volatile copper compounds

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Abstract

A copper(I) iminopyrrolidinate was synthesized and evaluated by thermal gravimetric analysis (TGA), solution based 1H NMR studies and surface chemistry to determine its thermal stability and decomposition mechanism. Copper(I) tert-butyl-imino-2,2-dimethylpyrrolidinate (1) demonstrated superior thermal stability and showed negligible decomposition in TGA experiments up to 300 °C as well as no decomposition in solutions at 165 °C over 3 weeks.

Graphical abstract: Preventing thermolysis: precursor design for volatile copper compounds

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Publication details

The article was received on 26 Jul 2012, accepted on 01 Sep 2012 and first published on 06 Sep 2012


Article type: Communication
DOI: 10.1039/C2CC35415B
Citation: Chem. Commun., 2012,48, 10440-10442
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    Preventing thermolysis: precursor design for volatile copper compounds

    J. P. Coyle, A. Kurek, P. J. Pallister, E. R. Sirianni, G. P. A. Yap and S. T. Barry, Chem. Commun., 2012, 48, 10440
    DOI: 10.1039/C2CC35415B

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