The redox effect of the [1,2-(NH)2C6H4]2− ligand in the formation of transition metal compounds

Francesca A. Stokes; Lars Kloo; Yaokang Lv; Philip J. Harford; Andrew E. H. Wheatley; Dominic S. Wright

doi:10.1039/C2CC35213C

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The redox effect of the [1,2-(NH)₂C₆H₄]²⁻ligand in the formation of transition metal compounds†

Francesca A. Stokes,^a Lars Kloo,^b Yaokang Lv,^a Philip J. Harford,^a Andrew E. H. Wheatley*^a and Dominic S. Wright*^a

Author affiliations

* Corresponding authors

^a Chemistry Department, Cambridge University, Lensfield Rd, Cambridge, UK
E-mail: aehw2@cam.ac.uk, dsw1000@cam.ac.uk

^b Department of Chemistry, Royal Institute of Technology, Teknikringen 36, Stockholm, Sweden
E-mail: larsa@kth.se

Abstract

Reactions of the [1,2-(NH)₂C₆H₄]²⁻ dianion (LH₂²⁻) with Cp₂M^II (M = V, Mn) lead to complete or partial oxidation of the metals (M), giving the V^III compound [(η⁵-Cp)(LH₂)₂VV(LH₂)]⁻[Li(THF)₄]⁺ (1) and Mn^II₄Mn^III₂ oxo cage [Mn₆(LH₂)₆(μ₆-O)(THF)₄] (2).

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Article information

DOI: https://doi.org/10.1039/C2CC35213C
Article type: Communication
Submitted: 19 Jul 2012
Accepted: 20 Aug 2012
First published: 21 Aug 2012

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Chem. Commun., 2012,48, 11298-11300

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The redox effect of the [1,2-(NH)₂C₆H₄]²⁻ ligand in the formation of transition metal compounds

F. A. Stokes, L. Kloo, Y. Lv, P. J. Harford, A. E. H. Wheatley and D. S. Wright, Chem. Commun., 2012, 48, 11298 DOI: 10.1039/C2CC35213C

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