Issue 84, 2012

Pd(OAc)2 catalyzed direct arylation of electron-deficient arenes without ligands or with monoprotected amino acid assistance

Abstract

An efficient arylation of electron-poor arenes has been developed without the addition of external ligands or in the presence of a catalytic monoprotected amino acid which assisted the reaction to proceed under mild conditions. The meta-selectivity was observed under both conditions.

Graphical abstract: Pd(OAc)2 catalyzed direct arylation of electron-deficient arenes without ligands or with monoprotected amino acid assistance

Supplementary files

Article information

Article type
Communication
Submitted
11 Jul 2012
Accepted
05 Sep 2012
First published
06 Sep 2012

Chem. Commun., 2012,48, 10437-10439

Pd(OAc)2 catalyzed direct arylation of electron-deficient arenes without ligands or with monoprotected amino acid assistance

Y. Wang, X. Guo, X. Zhu, R. Zhong, L. Cai and X. Hou, Chem. Commun., 2012, 48, 10437 DOI: 10.1039/C2CC34949C

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