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Issue 79, 2012
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Non-interpenetrated IRMOF-8: synthesis, activation, and gas sorption

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Abstract

The synthesis and successful activation of IRMOF-8 (Zn4O(ndc)3, ndc = naphthalene-2,6-dicarboxylate) is presented. Room temperature synthesis effectively suppresses interpenetration. Although conventional activation under reduced pressure leads to structural collapse, activation by flowing supercritical CO2 yields a guest-free material with a BET surface area of 4461 m2 g−1.

Graphical abstract: Non-interpenetrated IRMOF-8: synthesis, activation, and gas sorption

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Publication details

The article was received on 30 Jun 2012, accepted on 12 Aug 2012 and first published on 29 Aug 2012


Article type: Communication
DOI: 10.1039/C2CC34689C
Citation: Chem. Commun., 2012,48, 9828-9830
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    Non-interpenetrated IRMOF-8: synthesis, activation, and gas sorption

    J. I. Feldblyum, A. G. Wong-Foy and A. J. Matzger, Chem. Commun., 2012, 48, 9828
    DOI: 10.1039/C2CC34689C

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