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Issue 85, 2012
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Pd-catalyzed borylative cyclisation of 1,7-enynes

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Abstract

Reaction of a variety of 1,7-enynes with bis(pinacolato) diboron catalysed by Pd bis(trifluoroacetate) affords homoallylic and allylic boronates containing a six membered carbo- or heterocycle, by formation of C–C and C–B bonds

Graphical abstract: Pd-catalyzed borylative cyclisation of 1,7-enynes

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Publication details

The article was received on 21 Jun 2012, accepted on 16 Aug 2012 and first published on 24 Aug 2012


Article type: Communication
DOI: 10.1039/C2CC34468H
Citation: Chem. Commun., 2012,48, 10517-10519
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    Pd-catalyzed borylative cyclisation of 1,7-enynes

    V. Pardo-Rodríguez, E. Buñuel, D. Collado-Sanz and D. J. Cárdenas, Chem. Commun., 2012, 48, 10517
    DOI: 10.1039/C2CC34468H

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