Issue 82, 2012

Rare-earth cation effects on three-dimensional metal–organic rotaxane framework (MORF) self assembly

Abstract

A set of metal–organic rotaxane frameworks (MORFs) are constructed with the use of a tetraimidazolium macrocycle, the terephthalate dianion, and the trivalent lanthanide metal cations Nd(III), Sm(III), Eu(III) or Tb(III) and are reported herein. The specific choice of the metal cation allows for control of the structure and luminescent properties of the resulting molecular frameworks.

Graphical abstract: Rare-earth cation effects on three-dimensional metal–organic rotaxane framework (MORF) self assembly

Supplementary files

Article information

Article type
Communication
Submitted
12 Jun 2012
Accepted
29 Aug 2012
First published
31 Aug 2012

Chem. Commun., 2012,48, 10186-10188

Rare-earth cation effects on three-dimensional metal–organic rotaxane framework (MORF) self assembly

H. Gong, B. M. Rambo, C. A. Nelson, V. M. Lynch, X. Zhu and J. L. Sessler, Chem. Commun., 2012, 48, 10186 DOI: 10.1039/C2CC34200F

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