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Issue 67, 2012
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Highly regioselective synthesis of aryl chalcogenides through C–H functionalization of arenes

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Abstract

We report here the regioselective synthesis of aryl chalcogenides through the iridium-catalyzed meta C–H borylation followed by copper-catalyzed C–S coupling reaction with chalcogenide sources in one pot, giving the 3,5-disubstituted aryl chalcogenides with high regioselectivity and good yields.

Graphical abstract: Highly regioselective synthesis of aryl chalcogenides through C–H functionalization of arenes

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Publication details

The article was received on 01 Jun 2012, accepted on 03 Jul 2012 and first published on 04 Jul 2012


Article type: Communication
DOI: 10.1039/C2CC33950A
Citation: Chem. Commun., 2012,48, 8440-8442
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    Highly regioselective synthesis of aryl chalcogenides through C–H functionalization of arenes

    J. Cheng, C. Yi, T. Liu and C. Lee, Chem. Commun., 2012, 48, 8440
    DOI: 10.1039/C2CC33950A

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