Issue 50, 2012
From the journal:

Chemical Communications

Total synthesis of (−)-dysiherbaine†

Nelma Carurucan Celindro,a   Tae Woo Kima  and  Sung Ho Kang*a  

* Corresponding authors

a MIRC, Dept. of Chemistry, KAIST, Daejeon 305-701, Korea
E-mail: shkang@kaist.ac.kr
Fax: +82-42-350-2810
Tel: +82-42-350-2825

Abstract

The enantioselective synthesis of (−)-dysiherbaine (1) has been established with efficiency via a unique synthetic strategy involving the desymmetrization of 2-substituted glycerol to install a quaternary chiral carbon, which induces further stereochemistry in the bicyclic perhydrofuropyran through mercuriocyclization and epoxidation.

Graphical abstract: Total synthesis of (−)-dysiherbaine

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Article information

DOI
https://doi.org/10.1039/C2CC32736H
Article type
Communication
Submitted
18 Apr 2012
Accepted
03 May 2012
First published
17 May 2012

Chem. Commun., 2012,48, 6295-6297

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Total synthesis of (−)-dysiherbaine

N. C. Celindro, T. W. Kim and S. H. Kang, Chem. Commun., 2012, 48, 6295 DOI: 10.1039/C2CC32736H

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