Issue 54, 2012

Formation of a surface covalent organic framework based on polyester condensation

Abstract

The reaction between 1,3,5-tris(4-hydroxyphenyl)benzene and benzene-1,3,5-tricarbonyl trichloride leads to polyester condensation and formation of a novel COF on an Au(111) surface. The characterization performed in situ by means of variable temperature STM and XPS reveals the formation of an array of hexagonal cavities with ca. 2 nm size.

Graphical abstract: Formation of a surface covalent organic framework based on polyester condensation

Supplementary files

Article information

Article type
Communication
Submitted
29 Mar 2012
Accepted
14 Apr 2012
First published
16 Apr 2012

Chem. Commun., 2012,48, 6779-6781

Formation of a surface covalent organic framework based on polyester condensation

A. C. Marele, R. Mas-Ballesté, L. Terracciano, J. Rodríguez-Fernández, I. Berlanga, S. S. Alexandre, R. Otero, J. M. Gallego, F. Zamora and J. M. Gómez-Rodríguez, Chem. Commun., 2012, 48, 6779 DOI: 10.1039/C2CC32270F

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