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Issue 53, 2012
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Self-assembly of polyoxotungstate with tetrarhodium-oxo core: synthesis, structure and 183W NMR studies

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Abstract

A sandwich-type rhodium polyoxotungstate with unprecedented tetrarhodium-oxo core Na12[(Rh43–O)2(H2O)2)(H2W9O33)2]·38H2O (1) was obtained by hydrothermal reaction of rhodium(II) acetate and sodium tungstate; crystal structure was determined by X-ray diffractometry and was confirmed by 183W NMR data; 1 is active in electrocatalytic water oxidation.

Graphical abstract: Self-assembly of polyoxotungstate with tetrarhodium-oxo core: synthesis, structure and 183W NMR studies

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Publication details

The article was received on 07 Mar 2012, accepted on 12 May 2012 and first published on 15 May 2012


Article type: Communication
DOI: 10.1039/C2CC31692G
Citation: Chem. Commun., 2012,48, 6666-6668
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    Self-assembly of polyoxotungstate with tetrarhodium-oxo core: synthesis, structure and 183W NMR studies

    M. N. Sokolov, S. A. Adonin, P. A. Abramov, D. A. Mainichev, N. F. Zakharchuk and V. P. Fedin, Chem. Commun., 2012, 48, 6666
    DOI: 10.1039/C2CC31692G

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