A microporous, moisture-stable, and amine-functionalized metal–organic framework for highly selective separation of CO2 from CH4

Bizhen Yuan; Deyun Ma; Xi Wang; Zhong Li; Yingwei Li; Huimin Liu; Dehua He

doi:10.1039/C2CC16923A

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A microporous, moisture-stable, and amine-functionalized metal–organic framework for highly selective separation of CO₂ from CH₄†

Bizhen Yuan,^a Deyun Ma,^ab Xi Wang,^a Zhong Li,^a Yingwei Li,*^a Huimin Liu^c and Dehua He^c

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* Corresponding authors

^a School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China
E-mail: liyw@scut.edu.cn

^b College of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, China

^c Department of Chemistry, Tsinghua University, Beijing 100084, China

Abstract

A new microporous amino-functionalized metal–organic framework has been synthesized by direct self-assembly, which exhibits high moisture-stability, acceptable capacity, and unprecedented high selectivity for CO₂ over CH₄, suggesting its potential application in gas separation processes like natural gas and biogas upgrading.

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Article information

DOI: https://doi.org/10.1039/C2CC16923A
Article type: Communication
Submitted: 08 Nov 2011
Accepted: 01 Dec 2011
First published: 14 Dec 2011

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Chem. Commun., 2012,48, 1135-1137

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A microporous, moisture-stable, and amine-functionalized metal–organic framework for highly selective separation of CO₂ from CH₄

B. Yuan, D. Ma, X. Wang, Z. Li, Y. Li, H. Liu and D. He, Chem. Commun., 2012, 48, 1135 DOI: 10.1039/C2CC16923A

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