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Issue 13, 2012
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Synthesis of α-indanones via intramolecular direct arylation with cyclopropanol-derived homoenolates

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Abstract

A palladium-catalysed, tandem cyclopropanol rearrangement and direct arylation approach for the synthesis of 1-indanones is reported. The reaction is generally high yielding, uses oxygen as the terminal oxidant and tolerates a range of functional groups on the aryl ring.

Graphical abstract: Synthesis of α-indanones via intramolecular direct arylation with cyclopropanol-derived homoenolates

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Publication details

The article was received on 01 Nov 2011, accepted on 10 Dec 2011 and first published on 12 Dec 2011


Article type: Communication
DOI: 10.1039/C2CC16758A
Citation: Chem. Commun., 2012,48, 1922-1924
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    Synthesis of α-indanones via intramolecular direct arylation with cyclopropanol-derived homoenolates

    D. Rosa and A. Orellana, Chem. Commun., 2012, 48, 1922
    DOI: 10.1039/C2CC16758A

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