Issue 12, 2012

A [2+2] cross-photodimerisation of photostable olefinsvia a three-component cocrystal solid solution

Abstract

A ditopic hydrogen-bond-donor template in the form of resorcinol facilitates a [2+2] cross-photodimerisation of 4-Cl-stilbazole and 4-Me-stilbazole in a rare cocrystal solid solution. A photoreaction does not proceed with the olefins individually or as a solid solution composed solely of the two olefins.

Graphical abstract: A [2+2] cross-photodimerisation of photostable olefinsvia a three-component cocrystal solid solution

Supplementary files

Article information

Article type
Communication
Submitted
01 Sep 2011
Accepted
25 Nov 2011
First published
03 Jan 2012

Chem. Commun., 2012,48, 1790-1792

A [2+2] cross-photodimerisation of photostable olefinsvia a three-component cocrystal solid solution

D. Bučar, A. Sen, S. V. S. Mariappan and L. R. MacGillivray, Chem. Commun., 2012, 48, 1790 DOI: 10.1039/C2CC15453F

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