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Issue 1, 2012
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Phosphate ligands in the gold(I)-catalysed activation of enynes

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Abstract

Gold(I) forms neutral complexes with binol phosphates that are unreactive in the catalytic cyclisation of enynes. Reaction in protic solvents or activation by silver(I) restores the catalytic activity.

Graphical abstract: Phosphate ligands in the gold(i)-catalysed activation of enynes

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Publication details

The article was received on 16 Sep 2011, accepted on 20 Oct 2011 and first published on 04 Nov 2011


Article type: Communication
DOI: 10.1039/C1CC15739F
Citation: Chem. Commun., 2012,48, 52-54
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    Phosphate ligands in the gold(I)-catalysed activation of enynes

    M. Raducan, M. Moreno, C. Bour and A. M. Echavarren, Chem. Commun., 2012, 48, 52
    DOI: 10.1039/C1CC15739F

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