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Issue 1, 2012
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Evidence for atomic mixingvia multiple intermediates during the dynamic interconversion of silicate oligomers in solution

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Abstract

We investigate Si8- and Si16-based silicate species via global optimisation searches and ab initio calculations and propose a new multi-mechanism interpretation of the experimentally observed atomic mixing of silicate oligomers in solution.

Graphical abstract: Evidence for atomic mixingvia multiple intermediates during the dynamic interconversion of silicate oligomers in solution

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Publication details

The article was received on 29 Jul 2011, accepted on 28 Sep 2011 and first published on 14 Oct 2011


Article type: Communication
DOI: 10.1039/C1CC14674B
Citation: Chem. Commun., 2012,48, 46-48
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    Evidence for atomic mixingvia multiple intermediates during the dynamic interconversion of silicate oligomers in solution

    K. E. Jelfs, E. Flikkema and S. T. Bromley, Chem. Commun., 2012, 48, 46
    DOI: 10.1039/C1CC14674B

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