Catalytic hydroboration by an imido-hydrido complex of Mo(iv)†
Abstract
The imido-hydrido complex (ArN)Mo(H)(Cl)(PMe3)3 catalyses a variety of hydroboration reactions, including the first example of catalytic addition of HBCat to
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* Corresponding authors
a
Chemistry Department, Brock University, 500 Glenridge Ave., St. Catharines, ON, Canada
E-mail:
gnikonov@brocku.ca
Tel: +1 905 6885550, ext 3350
b
Kurnakov Institute of General and Inorganic Chemistry RAS, Leninskii Prosp. 31, Moscow, Russia
E-mail:
kuzmina@igic.ras.ru
The imido-hydrido complex (ArN)Mo(H)(Cl)(PMe3)3 catalyses a variety of hydroboration reactions, including the first example of catalytic addition of HBCat to
A. Y. Khalimon, P. Farha, L. G. Kuzmina and G. I. Nikonov, Chem. Commun., 2012, 48, 455 DOI: 10.1039/C1CC14508H
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