One-pot regioselective synthesis and X-ray crystal structure of a stable [60]fullerene trisadduct with the eedge,eface,trans-1 addition pattern

Maria Riala; Marios S. Markoulides; Eleni E. Moushi; Nikos Chronakis

doi:10.1039/C1CC15596B

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One-pot regioselective synthesis and X-ray crystal structure of a stable [60]fullerene trisadduct with the e_edge,e_face,trans-1 addition pattern†

Maria Riala,^a Marios S. Markoulides,^a Eleni E. Moushi^a and Nikos Chronakis*^a

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* Corresponding authors

^a Department of Chemistry, University of Cyprus, P. O. Box 20537, 1678 Nicosia, Cyprus
E-mail: nchronak@ucy.ac.cy
Fax: +357 22892801
Tel: +357 22892781

Abstract

The Bingel functionalisation of C₆₀ with a structurally novel tether equipped with three reactive malonate groups afforded a C_2v-symmetrical e_edge,e_face,trans-1 trisadduct in a complete regioselective manner and in an excellent yield of 65%. The [60]fullerene trisadduct showed pronounced ability to crystallise and gave X-ray quality single crystals for analysis.

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Article information

DOI: https://doi.org/10.1039/C1CC15596B
Article type: Communication
Submitted: 09 Sep 2011
Accepted: 22 Sep 2011
First published: 04 Oct 2011

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Chem. Commun., 2011,47, 11948-11950

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One-pot regioselective synthesis and X-ray crystal structure of a stable [60]fullerene trisadduct with the e_edge,e_face,trans-1 addition pattern

M. Riala, M. S. Markoulides, E. E. Moushi and N. Chronakis, Chem. Commun., 2011, 47, 11948 DOI: 10.1039/C1CC15596B

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