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Issue 45, 2011
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Structure, resolution and chiroptical analysis of stable lanthanide complexes of a pyridylphenylphosphinate triazacyclononane ligand

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Abstract

Lanthanide complexes of a pyridylphenylphosphinate ligand based on triazacyclononane form an isostructural series. The C3-symmetric Δ and Λ complexes of Eu and Tb are strongly emissive and can be resolved by chiral HPLC; the absolute configuration of each complex has been assigned using CD and CPL measurements.

Graphical abstract: Structure, resolution and chiroptical analysis of stable lanthanide complexes of a pyridylphenylphosphinate triazacyclononane ligand

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Publication details

The article was received on 08 Aug 2011, accepted on 23 Sep 2011 and first published on 19 Oct 2011


Article type: Communication
DOI: 10.1039/C1CC14904K
Citation: Chem. Commun., 2011,47, 12289-12291
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    Structure, resolution and chiroptical analysis of stable lanthanide complexes of a pyridylphenylphosphinate triazacyclononane ligand

    J. W. Walton, L. D. Bari, D. Parker, G. Pescitelli, H. Puschmann and D. S. Yufit, Chem. Commun., 2011, 47, 12289
    DOI: 10.1039/C1CC14904K

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