Issue 39, 2011
From the journal:

Chemical Communications

An oxidative coupling route to macrocyclic thiophenes and its application in the synthesis of a donor/acceptor hybrid molecule†

Stefan K. Maier,a   Stefan-S. Jester,a   Ute Müller,a   Walter M. Müllera  and  Sigurd Höger*a  

* Corresponding authors

a Universität Bonn, Kekulé-Institut für Organische Chemie und Biochemie, Gerhard-Domagk-Str. 1, 53121 Bonn, Germany
E-mail: hoeger@uni-bonn.de
Fax: +49 (0)228 73 5662
Tel: +49 (0)228 73 3495

Abstract

A route towards phenylene-bithiophene macrocyclesvia oxidative thiophene coupling under pseudo-high dilution conditions is reported. This method is applied to the synthesis of a shape-persistent thiophene macrocycle with extraannularly attached perylenebisimide moieties that forms supramolecular aggregates at the solid/liquid interface.

Graphical abstract: An oxidative coupling route to macrocyclic thiophenes and its application in the synthesis of a donor/acceptor hybrid molecule

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Article information

DOI
https://doi.org/10.1039/C1CC14664E
Article type
Communication
Submitted
29 Jul 2011
Accepted
26 Aug 2011
First published
12 Sep 2011

Chem. Commun., 2011,47, 11023-11025

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An oxidative coupling route to macrocyclic thiophenes and its application in the synthesis of a donor/acceptor hybrid molecule

S. K. Maier, Stefan-S. Jester, U. Müller, W. M. Müller and S. Höger, Chem. Commun., 2011, 47, 11023 DOI: 10.1039/C1CC14664E

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